产品说明
一般描述
Tetramethylammonium chloride (TMAC) is structurally similar to alkyltrimethylammonium salts. Oxidation of TMAC yields formaldehyde and trimethlamine. It is considered as poor phase-transfer catalyst for most reactions as it is insoluble in organic media. However, it is highly suitable as phase-transfer catalyst for fluorination of chlorobenzaldehydes along with alkali metal fluorides which yield 1,2,2,2-tetrafluoroethyldifluoromethyl ether.
应用
TMAC may be used in ion-exchange procedures to show the increase of pH in understanding the chemical behaviour of catalyst [CTA]Si-MCM-41 using Knoevenagel condensation model.
法律信息
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
基本信息
| 线性分子式 | (CH3)4N(Cl) |
| 分子量 | 109.60 |
| Beilstein | 3911201 |
| EC 号 | 200-880-8 |
| MDL编号 | MFCD00011628 |
| PubChem化学物质编号 | 329765550 |
| NACRES | NB.21 |
产品性质
| 质量水平 | 100 |
| 描述 | cationic |
| 测定 | ≥99.0% (AT) |
| 质量 | LiChropur™ |
| technique(s) | ion pair chromatography: suitable |
| mp | >300 ℃ (lit.) |
| λ | 10 % in H2O |
| 紫外吸收 | λ: 220 nm Amax: 0.05 λ: 230 nm Amax: 0.04 λ: 250 nm Amax: 0.03 λ: 260 nm Amax: 0.02 λ: 500 nm Amax: 0.02 |
| 适用性 | corresponds to standard for RP gradient test corresponds to standard for filter test |
| SMILES string | [Cl-].C[N+](C)(C)C |
| InChI | 1S/C4H12N.ClH/c1-5(2,3)4;/h1-4H3;1H/q+1;/p-1 |
| InChI key | OKIZCWYLBDKLSU-UHFFFAOYSA-M |
安全信息
| 象形图 | ![]() ![]() ![]() |
| 警示用语: | Danger |
| 危险声明 | H300 - H311 - H315 - H370 - H411 |
| 预防措施声明 | P260 - P264 - P273 - P280 - P301 + P310 - P302 + P352 + P312 |
| 危险分类 | Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Chronic 2 - Skin Irrit. 2 - STOT SE 1 Oral |
| 靶器官 | Central nervous system |
| 储存分类代码 | 6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials |
| WGK | WGK 1 |
| 个人防护装备 | Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges |

SUPELCO
